In view of the desire to reduce the use of fossil fuels and nuclear energy, the massive use of renewable energies for our energy needs has become a necessity. It is now becoming urgent to provide a response to the intermittency of certain renewable energies (wind and solar) in order to store excess production and respond to subsequent consumption peaks. The energy produced in this way must be stored in another form in order to avoid losses and ensure continuity of supply, particularly for electricity. This is known as Power-to-X, where Power is the energy produced and X is the medium used to store it pending consumption.

In this strategy, the production of energy carriers such as H2 is essential, hence the numerous projects involving the development of water electrolysis technology up to pilot production sites. Thus a fraction of the electrical surplus is consumed for the production of H2 by electrolysis: this is called Power-to-Gas (the vector produced, H2, being a gas). The difficulty of storing H2 remains a limiting factor in the medium to long term. In this perspective, various transformations are envisaged. The methanation reaction, by reaction between H2 and CO2, is a particularly attractive option, as the product is 100% miscible with natural gas and can therefore be injected directly into existing distribution networks. Many sources of recoverable CO2 exist: CO2 from biogas or syngas (biomass gasification) purification processes, CO2 capture from industrial emissions (particularly from cement, petrochemical and metallurgical processes) and emissions linked to electricity production (combustion production sites).

The CO2 hydrogenation reaction, in addition to being a way of reducing CO2 emissions, makes it possible to transform an energy carrier that is difficult to store and whose transport is restrictive (H2) into an energy compound that can be easily stored, and which can be transported and distributed over short or long distances via an existing infrastructure network (gas pipelines, LNG carriers).

The project proposes the optimisation of catalysts for the v-reaction, up to and including pilot validation. Two main stages are planned in the study: small-scale synthesis and evaluation in a micro-pilot; scaling up with the preparation of kg-scale batches and pilot testing on shaped material. The terms of reference for the proposed study:

  • Identification of three catalyst formulations without noble metal (Ni base, with secondary metal for improved activity/selectivity/stability)
  • Extrapolation and shaping of the identified catalyst formulations (1 kg each), with a mechanical strength of the prepared objects (granules of size 2-4 mm) greater than 10 N; Preparation of a benchmark supported noble metal catalyst
  • Long-term catalytic performance (severe conditions [CH4] = 20 vol.%; PH2 = 10 bar; VVH = 20,000 h-1; duration = 200 h): CO2 conversion > 90%; CH4 selectivity > 90%; initial activity maintenance > 90%.